316 vs 17-4 ph chloride corrosion cracking

Stress corrosion cracking properties of 17 4 ph steel. Unlike conventional martensitic stainless steels, such as type 410, 174. Nickel and nickel base alloys are normally resistant to chloride stress corrosion cracking as compared to stainless steels. Pitting and crevice corrosion can be avoided by either choosing a more corrosion resistant stainless steel or by changing the service environment so that it is less aggressive. Titanium is used as a stabilizing element in austenitic stainless steels with higher carbon contents, and will reduce the formation of chromium carbides. The corrosion tables provide an initial guide to the selection of materials and are intended to facilitate understanding of the different types of corrosion damage that can arise due to poor material selection.

Alloys 316, 316l, and 317l are more resistant to atmospheric and other mild types of corrosion than the 188 stainless steel. The alloys 304, 304l, and 304h are the most susceptible of the austenitic stainless steel to stress corrosion cracking scc in halides because of their relatively low nickel content. Although the general corrosion resistance of nitronic 60 is not quite as good as type 316, it does offer better chloride pitting resistance, stress corrosion cracking resistance, and crevice corrosion resistance than type 316 in laboratory conditions. Uses for 17 4 stainless steel include components which require high hardness andor corrosion resistance at temperatures of up to 600 f 316 c. Stress corrosion also called stress corrosion cracking or chloride stress corrosion. Maeda, the effect of sensitizing temperature on stress corrosion cracking of type 316 austenitic stainless steel in hydrochloric acid solution, corros. Very high strengths can be achieved with martensitic stainless steels, like grade 440c. This article will focus on two types in particular. Aisi 316l and 174 ph uns s17400, aisi 630 are two grades of wrought. This material was chosen because of corrosion resistance and its good fatigue life.

Chloride stress corrosion cracking in austenitic stainless. The important environmental factors that favor localized attack are higher chloride content, higher temperatures, lower ph, and more noble corrosion potentials. Chlorine dioxide clo 2, occurs naturally as a gas, but is normally dissolved in water, as the gas is highly explosive. Duplex alloys are more resistant to chloride stress corrosion cracking than types 304 and 316. High performance stainless steels nickel institute. The corrosion data in this section is mainly based on the results of general corrosion laboratory tests, which are not strictly comparable with actual service conditions. The most well known precipitation hardening steel is 174 ph. Hardening is achieved by a shorttime, simple lowtemperature treatment. Effect of aging temperature on stress corrosion cracking of. Chloride induced stress corrosion cracking in standard austenitic stainless steels, viz. Corrosion resistance of 174 ph stainless steel question. A recommended b fair see above c probably unsuitable d unsatisfactory not as corrosion resistant as 316 stainless steel fluid 17 4 ph stainless steel 75f 150f calcium hydroxide 20% a b calcium hypochlorite c carbon dioxide dry a a carbon tetrachloride dry a a carbon tetrachloride wet. Nitronic 60 replaces 304l and 316l in corrosive applications.

Developed more than 70 years ago in sweden precisely for the sulfite paper industry where the. Stress corrosion cracking facts and how to reduce the risk. Corrosion resistance of stainless steels contents 1. Stress corrosion cracking and fatigue crack growth behavior were determined in 17 4 ph stainless steel under various metallurgical conditions, including the h900 482c1 h, h1025 552c4 h. The advantageous effect of nickel on limiting the stress corrosion cracking in boiling 42% mgcl2 is observed. What are the strength requirements of the stainless steel. This has taken the form of a search of public domain literature and. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Recent unexpected occurrences of stresscorrosion cracking scc with 174 ph structural components indicated a need for improved characterization of the alloy and application of more advanced analytical procedures for reliably predicting structural performance.

Intergranular corrosion type 316 is susceptible to precipitation of chromium carbides in grain boundaries when exposed to temperatures in the 800 f to 1500 f 427 c to 816 c range. Chlorine dioxide as a sanitiser in contact with stainless steels. Chloride stress corrosion cracking the greatest corrosion advantage for duplex stainless steels is their improved resistance to cscc when compared to the austenitic grades. Type 316 stainless steel performs without evidence of corrosion in the 100hou, 5% salt spray astmb117 test. The ferritics are also ideally suited for roll forming to roofing, walling and rainwater goods. Effect of aging temperature on corrosion behavior of sintered 174. Corrosion tests are not normally performed on nitronic 60 hs.

The alloy is subject to brittle fractures and more sensitive to chloride stress corrosion cracking than the aged material. If risks of chloride stress corrosion cracking are present the higher aging temperatures should be selected over 1022f 550c, preferably 1094f 590c. Stress corrosion cracking in 174ph and 177ph stainless. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. High strength is maintained to approximately 600 degrees fahrenheit 316 degrees celsius. The use of type 174 ph stainless steel, which has a high resistance to corrosion, has been of. Ati 174 precipitation hardening stainless steel is furnished as plate, sheet, strip and long products. It can improve the aqueous corrosion resistance of welds made in higher carbon grades. Unlike conventional martensitic stainless steels, such as type 410, 17 4 is quite weldable. In general, the corrosion resistance of ati 17 4 alloy is superior to that of the hardenable 400 series stainless steels. Similar to crevice corrosion is galvanic corrosion which is also the result of low resistivity. The higher alloyed later generation grades give outstanding performance in heat exchanger and piping systems for chloridecontaining aqueous solutions and seawater, where stress corrosion cracking of austenitic grades can be a problem. Stainless steel 8, 155, 174, 177, 310, 303 su, 303. Aug 22, 2016 examples of these are grade 440c and 17 4 ph, respectively.

With respect to pitting and crevice corrosion resistance the high chromium, molybdenum and nitrogen contents in duplex grades provide very good resistance to chlorideinduced localized corrosion in aqueous environments. Rhodes, mechanism of chloride stress corrosion cracking of austenitic stainless steels, corrosion 25 1969 462467. Temperature the concentration of chloride increases with increasing temperatures, while the effect of hydrogen decreases owing to its increased mobility in the ferrite matrix. It is used in metal degreasing and cleaning processes in a wide range of industry applications. I am an engineer for a small aerospace manufacturing company and we are working on a part made from 174 ph stainless steel. Duplex stainless steel comparison to stainless steel 316l. I have industrial pumps made of 17 4 ss and 316 ss that are filled with di water and glycol 5050 which are rusting during the shipment process to the end user. Scully, mechanochemical anodic dissolution of austenitic stainless steel in hot chloride solution at controlled electrode potential, j. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Ferric chloride corrosion testing rolled alloys, inc. There are several types of stress corrosion cracking scc, for example, chloride induced scc and h 2 sinduced scc. A corrosive medium especially chloride bearing or hydrogensulphide h 2 s media. Corrosion behavior of inconel 625 heanjia super metals. Since pricing and corrosion resistance are both equally important when deciding a grade for a particular selection.

One known exception is highly oxidizing acids such as nitric acid to which the molybdenum. There can be a risk of stress corrosion cracking scc attack at higher temperatures, which is common to both the 304 and. Overaging aging beyond the peak strength condition improves resistance to stress corrosion cracking. Metline industries supplies high quality duplex stainless steel 2205 rods and bars, as well as stainless steel 316l stainless steel bars and rods. In this work the scc susceptibility of the precipitation hardening stainless steels 17. Inconel 625 is known for its strength, outstanding fabrication, welding and excellent corrosion resistance properties. It is important to discuss these variables for any application. Better stress corrosion cracking resistance comes with higher ageing temperatures.

Duplex 2205 stainless steel bar national specialty alloys. Pitting corrosion or crevice corrosion happens when the passive oxide film on an alloy surface breaks down in a chloriderich environment. Chloride stress corrosion cracking of aisi 316 stainless steel downhole pressure memory gauge cover. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. In addition to what edstainless mentioned, this part will be quite susceptible to stress corrosion cracking scc. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. The alloys are used widely in equipment and utensils for processing and handling of food, beverages, and dairy products. The use of type 17 4 ph stainless steel, which has a high resistance to corrosion, has been of great significant value in the paper industry. Both 304 and 316 stainless steel types are resistant to a wide range of concentration and temperature. Specific applications for 17 4 include the petroleum and chemical industries, as well as use in aircraft parts.

Corrosion resistance of the austenitic chromiumnickel stainless steels in chemical environments interpreting corrosion test data the quantitative data secured in corrosion tests are often of a very low order of magnitude. Corrosion resistance is similar to 304, with twice the strength of 316. General corrosion similar to relative austenitic alloys. For maximum resistance to chloride stress corrosion cracking, the alloy. Test method c in a923 is a ferric chloride pitting test. General corrosion the alloys 304, 304l, and 304h austenitic stainless steel provide useful resistance to corrosion on a wide range of moderately oxidizing to moderately reducing environments. The name comes from the chemical makeup which is approximately 17% chromium and 4% nickel. Next to water, chloride is the most common chemical found in nature. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. I have industrial pumps made of 174 ss and 316 ss that are filled with di water and glycol 5050 which are rusting during the shipment process to the end user.

When the cor rosion rate is of the order of less than 0. Recent unexpected occurrences of stresscorrosion cracking scc with 17 4 ph structural components indicated a need for improved characterization of the alloy and application of more advanced analytical procedures for reliably predicting structural performance. Jan 08, 2002 hydrogen sulfide, chloride and ph are the principal agents of sulfide stress corrosion cracking. Sae type 630 stainless steel more commonly known as 174 ph, or simply 174. Chloride stress corrosion cracking in austenitic stainless steel. Sae type 630 stainless steel is a grade of martensitic precipitation hardened stainless steel. Duplex 2205 stainless steel bar uns s31803uns s32205 uns s31803 and uns s32205 are commonly referred to as duplex 2205 material, whose duplex name is derived from the mixed microstructure which contains about equal portions of ferrite and austenite.

Alloy 174ph in the solutionannealed condition condition a should not generally be put in service. Corrosion behavior of inconel 625 heanjia super metals co. Actually, 316ti is a derivative of 316 in the same way that 321 is related to 304. They also suffer from pitting corrosion and transgranular stress corrosion cracking in chloridecontaining solutions 45. These alloys also offer higher creep, stresstorupture and tensile strength at elevated temperature. Alloy 174ph has corrosion resistance comparable to 304l in some chemical, dairy, food, paper and petroleum applications. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. This is because type 174 ph stainless steel has a higher yield pressure than carbon steel. Residual chlorine levels in waters of 2ppm maximum for 304 and 5ppm for 316 types should not normally be considered a crevice corrosion hazard.

This is because type 17 4 ph stainless steel has a higher yield pressure than carbon steel. The salt content in these environments ranges from 10,000 19,000 mgl of chlorides. The alloys comprising of 42 45% nickel will not be attacked in this. Corrosion of carbon steel digesters has been a perennial design problem.

Effect of aging temperature on stress corrosion cracking. In warm chloride environments, 174 ph is susceptible to pitting and. In most environments, the ppm are so small the effects on stainless are minute. How to select the right stainless steel for adequate corrosion resistance structural applications other applications 5. Laboratory failure analysis attributed the damage to chloride stress corrosion cracking phenomena and was followed by a study on the behaviour of 174 ph in chloriderich environments and on the. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. This alloy is designated grade or type 630 in several specifications. For example, lower service temperatures or reduced levels of chloride can substantially reduce the aggressiveness of the environment. Prevention of corrosion of inconel alloy 625 at the diverse temperatures and corrosive conditions is the basic need for its extensive acceptance in the chemical processing and other applications. Wear and galling resistance are increased using this material, especially when self mated. Effect of temperature on the pitting resistance of s44660 super ferritic stainless steel in 6% ferric chloride test solution.

In case of duplex and stainless steel 316, there is no clear winner. Ati 174 precipitation hardening stainless steel s17400, type 630, is a chromiumnickelcopper precipitation hardening. The corrosion tables provide an initial guide to the selection of materials and are intended to facilitate understanding of the different types of corrosion. Alloy 174 ph precipitation hardening sandmeyer steel. Austenitic stainless steels, such as grade 316, can provide. Examples of these are grade 440c and 174 ph, respectively. Corrosion tables the corrosion data in this section is mainly based on the results of general corrosion laboratory tests, which are not strictly comparable with actual service conditions. Types 316 and 316l are molybdenumbearing austenitic stainless steel which are more resistant to general corrosion and pittingcrevice corrosion than the conventional chromium nickel austenitic stainless steel such as type 304. Stainless steels types 304 and 316 can be considered resistant below 80 degc, up to the limit of solubility. What is the difference between 174 and 316l stainless steel.

The duplex microstructure gives this grade high strength, excellent resistance to chloride stress corrosion cracking, high thermal conductivity, and a low coefficient of thermal expansion. Selection of stainless steels for handling chlorine. You really need to change to something more appropriate, such as a duplex grade like 2205 or a nickel or titaniumbased. As with other precipitation hardening stainless steels, ati 17 4 precipitation hardening stainless steel is more susceptible to stress corrosion cracking at peak strength. Chlorides are probably the single biggest enemy of stainless steel. Precipitation hardening stainless steels alloys, properties. Below 80 degc they can be considered resistant to any concentration of sodium hydroxide, up to the limit of solubility. Selection of stainless steels for handling chlorine cl2. Although the general corrosion resistance of nitronic 60 is not quite as good as type 316, it does offer better chloride pitting resistance, stress corrosion cracking resistance and crevice corrosion resistance than type 316 in laboratory conditions.